Direct synthesis of alkylsilanes by platinum-catalyzed coupling of hydrosilanes and iodoalkanes

Inubushi, Hikaru and Kondo, Hitoshi and Lesbani, Aldes and Miyachi, Mariko and Yamanoi, Yoshinori and Nishihara, Hiroshi Direct synthesis of alkylsilanes by platinum-catalyzed coupling of hydrosilanes and iodoalkanes. Chemical Communications.

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    Abstract

    Alkyl iodides and tertiary silanes were successfully coupled with good functional group tolerance using a Pt(P(tBu)3)2/(iPr)2EtN/ CH3CN system. The utility of the methodology is demonstrated by the synthesis of silafluofen, a Si-containing insecticide

    Item Type: Article
    Subjects: Q Science > QD Chemistry
    Divisions: Faculty of Mathematics and Natural Sciences > Department of Chemistry
    Depositing User: Mr Aldes Lesbani
    Date Deposited: 08 Oct 2014 11:26
    Last Modified: 08 Oct 2014 11:26
    URI: http://eprints.unsri.ac.id/id/eprint/4770

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