Synthesis of Tris(4-Methoxyphenyl)Phenylsilane Using Phenylsilane and 4-Iodo Anisole Catalyzed by Palladium Complex

Lesbani, Aldes and Mohadi, Risfidian and Eliza, Eliza and Mardiyanto, Mardiyanto Synthesis of Tris(4-Methoxyphenyl)Phenylsilane Using Phenylsilane and 4-Iodo Anisole Catalyzed by Palladium Complex. Makara Seri Science.

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    Abstract

    The synthesis of tris(4-methoxyphenyl)phenylsilan through the coupling reaction of phenylsilane and 4-iodoanisole using palladium tertiary tributylphosphine as a catalyst was carried out through the determination of the base, solvent, and reaction time. The results showed that tris(4-methoxyphenyl)phenylsilane can be synthesized to form maximum yield using 1,4-diazabicyclo[2,2,2]octane (DABCO) as a base, tetrahydrofuran as a solvent, and a 5-day reaction time. The highest yield of tris(4-methoxyphenyl)phenylsilane was 35%.

    Item Type: Article
    Subjects: Q Science > QD Chemistry
    Divisions: Faculty of Mathematics and Natural Sciences > Department of Chemistry
    Depositing User: Mr Aldes Lesbani
    Date Deposited: 08 Oct 2014 11:26
    Last Modified: 08 Oct 2014 11:26
    URI: http://eprints.unsri.ac.id/id/eprint/4763

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